Condensation polymers like PET, polyamide and polycarbonate tend to degrade during processing. Degradation is caused by a loss of molecular weight, which leads to loss of important material properties, especially melt strength and processability. The result is that recycled and reclaimed material of these types are often limited to applications that do not require high performance properties or, even worse, are rejected as unusable waste.
Though several technologies exist to reclaim degraded polymers; there is a need for a simple, efficient and low-cost technology that can reduce the loss of molecular weight and physical properties in reclaimed condensation polymers.
Clariant's recently developed �CESA-extend� chain extender (CE) is a new additive technology that offers such a solution. This epoxy-functional styrene/acrylic oligomer, provided as a masterbatch in a variety of carrier resins, can be added to degrade condensation resins to re-link broken polymer chains in an extruder. Ideally, the polymer chains are re-linked in linear chain extensions, with minimal crosslinking�thus the term �chain extender� to describe this additive and its function.

During the extrusion process, CE has been shown to react with polymer end groups via step-growth kinetics, with minimum crosslinking or gel formation. It has strong reactivity with amine, anhydride, isocyanate, carboxyl and hydroxyl end groups. Four laboratory studies recently investigated the effect of this additive as a chain extender for various condensation polymers. Test data measured the value added to reclaimed condensation resins as indicated by four key characteristics: melt strength and processability, mechanical properties (Izod impact and tensile strength), hydrolytic stability, and clarity (light transmission).

A great concern in using recycled PET is its dramatically reduced melt strength, which makes it very difficult to process by extrusion. A practical measure of PET melt strength is its resistance to sag when extruded into a sheet or profile. A test compared the degree of sag in an extrudate from a recycled extrusion-grade PET with that of identical material extruded with CE masterbatch in four different letdowns: 0.25%, 0.5%, 1.0% and 2.0%. The test was run on a 27-mm twin-screw extruder, operating at a constant melt temperature and screw speed, with an 8-in. sheet die and downstream pick-up rolls. The rolls were aligned with the die lip and operated at a constant speed, with the first one positioned 6.25 in. from the die lip. Sag was calculated by subtracting the lowest point of the extrudate, relative to the floor, from the height of the die lip. As the concentration of CE masterbatch was increased, the melt strength of the material increased, resulting in less sag or no sag at all in the case of 2% CE concentration.

Environmental moisture can cause hydrolysis and molecular-weight degradation in PC and PC/ABS alloys, even when in storage under normal conditions of humidity and temperature. Polar pigments such as TiO2 accelerate such degradation, so that just a few days of storage can measurably increase the melt-flow index of these alloys. The potential costs to processors of any hydrolytic degradation problems are likely to rise, because the trend is to require ever longer periods of hydrolytic stability and property retention in automotive, electrical, and electronic products made of these materials. An assessment was made to measure varying levels of CE additive that could reduce or compensate for the degradation occurring in a 70/30 PC/ABS blend during a seven-day accelerated test. The four PC/ABS samples tested included two untreated controls in pellet and extruded forms, and two samples containing 0.5% and 1.0% concentration of CE additive. All were exposed to 100% relative humidity at 95 C in a constant-humidity chamber for seven days. The MFR for each sample was measured daily.
Addition of CE additive dramatically reduced hydrolytic degradation of this polymer, enabling it to retain desirable MFR values far longer than control samples. Both control samples show extensive degradation, as evidenced by a 65% increase in MFR. In contrast, there is a noticeable chain-extension effect in the CE-treated samples. Not only did they have lower MFR than the controls at the outset, but they also showed a slower rate of degradation throughout the test.
Use of 0.5% CE fully compensated for the degradation effects seen in the test, so that Day 7 MFR for the treated sample was equal to that of Day 0 for the control. The chain extension was even more significant at the 1% concentration, with this sample showing extremely high levels of hydrolytic stability and negligible degradation.

Multilayer PET bottles with a barrier layer of aromatic nylon have been considered impossible to reprocess, due to the poor physical properties of the reground PET/polyamide blend. An impact of the CE additive on the processability of reclaimed PET/polyamide was assessed. Multilayer PET bottle preforms were ground and divided in three samples: a control and treated samples with 1% and 2% CE. A dramatic improvement in properties of all CE-treated samples, with those containing 1% CE performing as well as or better than those with higher CE concentrations took place. Unnotched Izod impact of 1% CE treated samples are 20% higher than the control samples and identical to the 2% CE samples. The melt viscosity of 1% CE-treated samples is more than 11 times higher than that of the controls and identical to the 2% CE-treated samples. Tensile strength of 1% CE-treated samples is 30% higher than the control samples and slightly above those of the 2% CE treated samples.
At 0.5% and 1.0% CE treated samples showed no loss of clarity or light transmission with masterbatches having PS and PET carriers, while polyolefin carriers lowered light transmission at all addition levels. Some loss of clarity was seen in PET film samples containing 2% CE in a PET carrier.