Packaging of foods is a major outlet for plastics in packaging
with an estimated share of 55% in case of flexible packaging materials
such as Coextruded Multilayer Films and Laminates. With an ever
growing requirement of ready-to-use convenience foods, packaging
has to play an important role to meet the performance requirements
of a products with respect to compatibility, barrier properties,
sterilization methods, shelf-life and last but perhaps the most
important, the aesthetic (sales) appeal. Some trends are wrapped-up
in the following paras :
RETORT PACKAGING :
Retortable flexible packaging materials
are defined by the ASTM as 'those capable of withstanding specified
thermal processing in a closed retort at temperature over 100 �C'.
Some products are retorted upro 130�C for 40 minutes.
Retortable package must maintain their material integrity as well
as their required barrier properties for their designated end-product
during products - to package handling, thermal processing and subsequent
handling and transport abuse. For shelf-stable foods, the materials
used must be retortable and still maintain extended barrier characteristics
against such effects as light, moisture, oxygen, microbial penetration,
etc. The polymers most commonly used by coextrusion are PET, PC
and PP. Low acid, homogeneous and small particle foods are tending
towards aseptic packaging, whereas retort packaging is preferred
for low acid foods with moderate to large-size particles because
of ease of removing oxygen from the head space by gas flushing and
also because a crisp texture obtained through freezing is possible
only with the retort packaging system.
Convenience and ready-to-serve foods are generally warmed-up in
microwave ovens. Few consumers would use conventional ovens, since
the concept of fast foods is totally lost if one has to wait for
30-40 min to serve, which is the case if conventional ovens are
used. The current demand is for the dual-ovenable retort concept.
Microwavable retort packages, on the hand, offer consumers convenience
and time saving. With the availability of microwave ovens indigenously,
the demand for such packaging is expected to grow very rapidly.
The important properties of a retort container are shelf-life, dimensional
stability through the retort and abuse resistance in shipping. Coextrusion
offers the greatest potential for retort packages but material selection
is critical, especially in areas of structural and physical properties,
gas and moisture barrier properties, and adhesive compatibility.
Material Selection :
The selection of a polymer and combination
is based on the requirement of barrier properties. They are in the
form of flexible pouches of coextruded and/or laminated films of
PET, PC, PP with aluminium foil, thermoformed when it comes to trays
and containers by injection blow-moulding process. Where a glass
look is desired, PC offers excellent optics and low haze for improved
products identification and market share. A coextruded structure
on PC has four time the relative modulus at 250 �C of coextrusion
based on filled PP. In addition, PC improves the tensile strength
of a container. Ease and flexibility of processing also come into
play here. A material must be able to be blow moulded, or extruded
and thermoformed. Both PP and PC can be extruded and blow-moulded.
However, PC has an advantage when it comes to thermoforming because
it is amorphous and thus has a wider thermoforming window. In most
extrusions, the structural layer is printed. Unlike PP, PC needs
no special treatment before printing. The barrier properties of
the materials within a coextruded package determine the shelf life.
For expended shelf-life, moisture and oxygen barrier is needed.
EVOH and PVDE offer the lowest oxygen permeation rates for retortable
applications. Considering all the factors, PC and EVOH appear to
offer the most promise in restorable high oxygen-barrier applications.
To sum up, the best structure available for a microwavable retort
container is a five-layer coextrusion with PP the food contact.
RETORT POUCH :
The term is used to describe a flexible package
into which a good product is placed, sealed and then sterilized at
temperatures in excess of 100 �C. Generally the process temperature
is between 110 - 140 �C. Most foods with a pH above 4.5 requires this
type of process. The finished product is commercially sterile, shelf-stable,
and requiring no refrigeration. The term 'retort' itself refers to
the pressurized container in which packaged foods are cooked by the
food processor. Manufacture
Retort pouches are made from laminates such as polyester/aluminium
foil/modified high-density polyethylene or polyester / aluminium foil/propylene-ethylene
copolymer. Some two-ply laminates give the longer shelf-life, the
aluminium foil supplying a complete barrier to oxygen, moisture and
light (provided that heat seal integrity is maintained). The latter,
of course, depends on the material use for the inner ply of laminate.
The outer ply must be tough, withstand abrasion and give good print
quality. The adhesive used to laminate the various plies is important
because of the dangers of delamination during storage and transit.
Seal integrity is easier to achieve using pre-made pouches where three
seams can virtually be guaranteed. However, reel stock is also used
and pouches are formed, filled and sealed on the appropriate equipment.
When pre-made pouches are used, the filling equipment consists of
rigid, open mouth plastic containers mounted on a re-circulating conveyor
system. At the appropriate point in the system, the plastic container
empties its contents into the pouch then returns for washing and refilling.
The foregoing description applies to solid products, such as pieces
of fish, hamburgers, etc. Liquids, such as sauces for fish, are filled
from an integral hopper. After filling, the machine removes head space
air and the pouch is sealed, using a double heat seal to minimize
the risk of faulty seals. The seal is cooled and the pouch passes
on to a rotating reservoir for loading on to the retort tray. A residual
air level of below 2% pouch capacity is normally achieved. Retort
or autoclave systems are based either on water or steam and air. The
latter system is more expensive but employs less energy in the long
term. Pouches, unlike cans, should not be agitated during the processing
period because the burst strength of the pouch decreases as the pouch
temperature is increased.
After removal from the retort, the pouches are dried and overwrapped
with a polyester/polyethylene laminate or placed into pre-erected
cartons. Although the retort pouch is tough and resists a great deal
of abuse, it is normally the practice to overwrap or place it in an
outer carton as a moisture-barrier layer. A trim layer next tot he
PP layer improves the economics. An adhesive layer bonds the scrap
tot he oxygen-barrier EVOH layer. Lastly, second ties layer bonds
the PC outside structural layer to the EVOH layer.
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