| Plastic fuel tanks in automobiles are gaining 
                                usage globally. Blow moulded or injection moulded 
                                multi layer HDPE fuel tanks are most common. The 
                                automotive industry has made significant developments 
                                to meet the recent emission standards.
 However this trend has not been increasing globally 
                              in a geographically uniform pattern. Europe has 
                              almost fully converted to these plastic fuel tanks, 
                              with 92% automobiles of European origin fitted with 
                              plastic fuel tanks. North America, with 75% usage, 
                              is lagging behind. However, the Asian region is 
                              lagging far behind, due to problems of economies. 
                              One of the possible reasons is the smaller number 
                              of car produced in different parts of Asia as compared 
                              to Europe and North America. The use of plastic 
                              fuel tank does not become economical at lower production 
                              levels of an individual automobile company.
 
 Another development in the auto segment has been 
                              plastic fuel lines that convey fuel from the tank 
                              to the engine compartment. Compared with existing 
                              rubber and steel fuel lines, plastic fuel lines 
                              are lighter in weight, lower in cost and often less 
                              permeable. They are also available in many colors, 
                              which make it easier to place, track and connect 
                              fuel supplies. Interestingly, the automotive companies 
                              are very slow in making the switch to plastic lines. 
                              The slower pace stems from concerns by auto companies 
                              over the ability of plastic fuel lines to meet strict 
                              air emission standards, and to resist electrostatic 
                              discharges (ESDs), which could ignite flammable 
                              fuels. Automakers also need to be convinced that 
                              fuel lines made of plastics can withstand the impact 
                              of crashes at low winter temperatures and can resist 
                              degradation from alcohol fuels. But polymer suppliers 
                              and Tier One auto manufacturers have developed new 
                              fuel line materials and designs, which they believe 
                              can meet these challenges.
 
 The most common polymer used in plastic fuel lines 
                              is polyamide, often combined in multilayer structures 
                              with fluorocarbon polymer barrier resins. Another 
                              low-permeability material that has been paired with 
                              polyamide in multilayer structures is polybutylene 
                              naphthalate (PBN). Aliphatic polyketones have also 
                              been promoted as fuel line materials. Some polymide 
                              based fuel line formulations include low levels 
                              of carbon nanotubes, which enhance ESD properties 
                              without harming physical properties.
 
 Complying with increasingly stringent antipollution 
                              regulations is the biggest challenge faced by developers 
                              of plastic fuel lines and other plastic fuel components 
                              such as tanks, pumps, vapor recovery systems, filter 
                              pipes and fuel rails. Of most concern to the global 
                              auto industry are regulations in the U.S. state 
                              of California that limit the levels of hydrocarbons 
                              auto fuel system can release into the air. Among 
                              them are the ZEV (zero emission vehicle), PZEV (partial 
                              zero emission vehicle), and the CARB (California 
                              Air Resource Board) LEV (low-emission vehicle) II 
                              standards. Some of these rules have already taken 
                              effect; others will be phased in over the next few 
                              years. Because California has traditionally set 
                              the pace for air pollution regulations in the rest 
                              of the U.S. and elsewhere, most of the world's car 
                              manufacturers are striving to meet the standards 
                              in that state.
 
 To meet the new air quality standards, plastic fuel 
                              line manufacturers have developed structures that 
                              reduce vapor permeation through their walls.
 Atofina Chemicals Inc. has developed tubes made 
                              from Rilsan line of polyamide 11 and 12, with barrier 
                              properties enhanced by coextrusion with Kynar PVDF 
                              (polyvinylidene difluoride). The layers are held 
                              together with an adhesive tie resin. Features of 
                              Atofina's new conductive grade of the Rilsan polyamide 
                              12 polymer include a surface resistivity below 105 
                              ohms which meets the conductivity requirements of 
                              SAE standard 2260, and impact resistance down to 
                              -40° C.
 Dana Corp. has commenced production of new multilayer 
                              plastic fuel line systems for automotive applications 
                              in Europe, North America and South America. The 
                              five-layer tubes have a PBN middle layer, two adhesive 
                              layers, and nylon 12 internal and external layers.The 
                              PBN-based materials are lower in permeation rates, 
                              cost and weight than polyamide/fluoropolymer multilayer 
                              fuel lines, and help in ahieving 2006 PZEV requirements.
 In Japan, Ube Industries and Asahi Glass, have jointly 
                              developed a two-layer fuel line material composed 
                              of nylon 12 and a ETFE (ethylene tetra fluro ethylene 
                              ), a barrier resin. The two layers in their resin 
                              system adhere strongly without the need for adhesive 
                              tie layers, which can deteriorate over time and 
                              cause delamination, and are reported to remain intact 
                              and undetached even after 1,000 hours of immersion 
                              in alcohol-based fuel. Other features include little 
                              fuel permeation or vaporization, and excellent machinability 
                              and chemical resistance.
 DuPont's product line known as Selar RB amorphous 
                              nylon can be dry blended with polyethylene to create 
                              monolayer fuel tanks, fuel lines, filler necks and 
                              filter housings that meet LEV II emission requirements.
 SRI International is offering for license a high-performance 
                              aliphatic polyketone, tradenamed Carilon, that combines 
                              good chemical and permeation resistance with superior 
                              impact strength and high-temperature performance.
 New ways for improving the ESD properties of 
                                fuel lines are also emerging. The typical approach 
                                for making a plastic fuel line static dissipative 
                                is to add graphite fibers to the resin formulation. 
                                But this can degrade the polymer's properties, 
                                particularly its impact strength. A newer practice 
                                is to make fuel line resins conductive with much 
                                smaller particles (carbon nanotubes). 
 Will these new material/product innovations accelerate 
                                the use of plastics in fuel lines?
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