Exaltec- a company jointly formed in 1998 by Bayer and GE (two largest manufacturers of Polycarbonate) to mainly develop a special coating to provide scratch resistance to Polycarbonate (PC) sheet so that it can be used for glazing of automobile, has finally seen the end of the tunnel. In June 2005, The U.S. Dept. of Transportation's National Highway Traffic Safety Administration (NHTSA) approved the Exaltec 900 material and coating system for all non-windshield glazing, provided that it meets all existing auto glazing specifications for laminated glass. NHTSA determined that no new regulations were necessary, PC glazing can be validated using existing specifications for laminated glass.
Polycarbonate has dominated the
market for vehicle headlamp covers for 15 years
and n ews from the auto industry is quite positive
that Polycarbonate sheets will find application
in automobile glazing shortly. PC glazing is being
moulded into larger parts offering considerable
weight saving and offer styling and design potential
(distinctive 3D shapes) that glass cannot match.
This emerging market holds good potential, but
will be challenging as Polycarbonate (PC) car
windows require specialized machinery, high-end
processing capability, premium polymers, advanced
coating technologies and innovative mould and
runner designs. Glass auto windows are produced
up to 1.5 or even 2 m 2
. With the latest technology, PC auto glazing
can be molded up to 1.4 m 2
(around 15 ft 2 ), although
some believe sizes up to 2 m 2
(21.5 ft 2 ) are expected
very soon. Larger auto glazing can deliver weight
savings up to 50% versus glass.
Unlike glass, PC glazing can have integral ribs
or brackets to lock the parts onto the vehicle
or support another feature. PC auto-glazing will
also introduce design concepts such as a side
window with the rear-view mirror mounted on it
rather than on the door panel, vehicle roofs that
wrap onto the rear of the vehicle, and moulded
heating/defrosting elements and radio antennas
into a PC window panel with in-mould films that
have preprinted circuitry.
Recent developments in scratch-resistant coating
systems have significantly broadened the PC glazing
market in the U.S. Until last June, PC was limited
in the U.S. to non-passenger areas of the vehicle,
typically in back cargo areas of SUVs, though
there are no such applications yet in the U.S.
Regulations are less stringent in Europe and Asia.
Manufacturing of PC auto-glazing requires a special set of manufacturing techniques that go beyond the conventional in machinery, moulds, materials, and processing methods.
First, the new auto glazing parts are large -
up to 1.4 m2 (around 15
ft2)�and they must to be
moulded under low-stress conditions for optical
quality and for retention of a hard coat. Residual
stresses in the part negatively influence optical
quality. High stress in the part can lead to haze
or delamination of the coating. Injection-compression
rather than conventional injection molding is
the ideal process for making large parts with
low stress. Machinery suppliers such as Battenfeld,
Engel and Krauss Maffei have developed injection-compression
processes to meet these low-pressure, low-stress
requirements. Because large glazing panels are
essentially thin-wall parts and must have parallel
surfaces for good optical qualities, moulding
machines must be able to maintain close parallelism
of platens and molds�within 0.1 mm.
New tooling concepts have been developed by European firms and hot-runner designs have also affected by the new moulding criteria.
New PC materials had to be developed for good flow, higher optical clarity than conventional materials, and adhesion to a hard coat. Bayer MaterialScience and GE each developed advanced PC resins with part thickness averages 4 to 5 mm, and the flow-length to thickness ratio is around 300:1.
Simutaneously, advances were imperative in post-mould coating technology to deliver high resistance to abrasion, scratching and UV exposure/ weathering, as well as good light transmission and anti-reflective properties. This led to proprietary �wet-coat� formulations as well as a new wet-coat/plasma-coating technique. |