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5 key characteristics of Carbon black grades to meet stringent requirements of plastic pipes

5 key characteristics of Carbon black grades to meet stringent requirements of plastic pipes

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5 key characteristics of Carbon black grades to meet stringent requirements of plastic pipes
5 key characteristics of Carbon black grades to meet stringent requirements of plastic pip ...  
 

Plastic pipes are increasingly used for pressure applications such as potable water supply etc. Higher pressure ratings, particularly of PE pipes, have been increasingly gaining higher market share. For instance, most of the recent PE pipes fall in the category of P100 pressure ratings. To meet the requirements of enhanced pressure rating, weathering is the most crucial property primarily dependent on the quality of Carbon black. All the major Carbon black suppliers have been developing improved grades. The critical requirements of Carbon black are:

 Long-term

 Long-term weatherability
The end product is required by utility companies to provide long service life without failure, despite being exposed to ultraviolet light. This requires very fine prime particles, which present more surfaces to incident light, and hence have greater UV light absorbing efficiency than a coarser particle size.

 Extremely

 Extremely low levels of moisture absorption
Compounds containing carbon black usually absorb moisture when exposed to air. This can create processing problems, surface defects or internal cavities in the finished part. The high purity of the carbon black grades developed for this application has resulted in very low moisture absorption during the compounding process.

 Dispersability

 Dispersability
This performance measure depends primarily on the fundamental characteristics of carbon black and relates to the attractive force needed to separate the agglomerates into discrete carbon black aggregates. It is also an indicator of the relative yields that can be achieved on compounding equipment with different carbon black grades. The P-types show much better dispersability than a conventional grade, resulting in better wetting with the polymer and subsequent de-agglomeration.

 Microscopic  Microscopic dispersion
Undispersed carbon black agglomerates in the pipe wall can lead to premature failure and also reduce fluid flow properties. These problems are recognised in the industry, and most standards for pressure pipes specify a microscopic dispersion rating of no greater than 3 under ISO 11420, NFT51 - 142. Conventional blacks typically rate between 5 and 6.

 Chemical

 Chemical cleanliness
Chemical impurities, particularly sulphur, ash and toluene extract, when present in the compounds used to make pipes for drinking water, can impart unpleasant tastes or odours. All carbon blacks include some residues of these materials, but in the P-type grades the amounts have been greatly reduced. For example, sulphur content - typically around 10,000 ppm in a conventional black - is some 600 ppm in the new grades.

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