Plastics consumption totaled to about 170
million tons in 2005 and continues to show
a healthy growth of more than the global GDP
(about 4-5% compared to 2-3 % GDP growth).
With about 35% of its consumption being in
packaging, plastics more often ends up faster
in municipal waste as well as on public places
or roads etc. Being lighter in weight compared
to other conventional packaging material,
it spreads all over making the environment
very dirty. Furthermore, the littering habits
of humans with limited literacy particularly
from the developing nations, causes the thinner
and light weight plastics products such as
film and even PET bottles to clutter roads,
beaches and parks. Being lighter and having
higher volumes compared to their weights,
they often tend to clog drainage etc., causing
flooding. Flooding that happened in Mumbai,
India during July 2005 was mainly due to very
heavy rainfall. But plastics film was blamed
because it choked the drains; not allowing
floodwater to get drained into the sea. This
has resulted into tighter civic laws - possibly
of permitting only thicker bag (greater than
50 micron) to be used in future.
One solution for restricting such environmental
problem is to convert plastic that is nothing
but solidified oil to degradable product that
ultimately mixes with soil and produces harmless
byproducts not causing any environmental problems.
Degradation is the process that would destroy plastic product partially or
completely. Generally degradation of plastic
is considered detrimental as it reduces the
usefulness of plastic. Additives such as antioxidants
for all polymers and heat stabilizers for
vinyl polymers are required to be incorporated
in order that these polymers remain stable
during their service life. Among all applications,
packaging has a very short life cycle of as
little as 3 months to as high as 1 year. After
that plastic packaging products cease to be
useful. They not only damage the environment
but also could upset the ecological balance.
Besides degradation, there are other means
to make the plastics disappear without damaging
environment. The first method that was used
very extensively from the beginning and is
still employed in many countries all over
the World is called �Land filling�. In this
process, the plastic product after its service
life, is put into the land. However as time
elapsed the land available for such purpose
got reduced drastically.
The second alternative is to utilize the calorific
value of plastic and put it in incineration.
However, typically the municipal waste of
plastic contains vinyl product that corrodes
incinerators due to the presence of halogen
(chlorine). Separation method can be used
to separate heavier fraction of vinyl from
the rest of plastic waste but it costs more.
This method seeks the energy from energy rich
plastic (solidified oil molecules). While
this possibly is the best option, it requires
a large amount of plastics at one place to
achieve the optimal level of use. The transportation
of plastic product for such use increases
cost.
Degradation is therefore considered to be
the safest and possibly one of the best alternatives.
Degradation of plastic can be achieved by
several methods. Oxygen, light, heat and ultra
violet rays are some of the means by which
degradation of plastic can be achieved.
The most useful and economic of the new technologies is wherein plastics
degrades by a process of OXO-degradation.
This technology is based on a very small amount
of a pro-degradant additive being introduced
into the conventional manufacturing process,
thereby changing the behaviour of the plastic.
The degradation of the plastic starts immediately
after manufacture and will accelerate when
exposed to heat, light or stress. It will
be consumed by bacteria and fungi after the
molecular structure has been reduced by the
additive to a level which permits living microorganism
access to the carbon and hydrogen. It can
therefore be properly described as �biodegradable�.
The material then ceases to be a plastic and
becomes a food source. This process continues
until the material has biodegraded to nothing
more than
CO2,
water and humus. It does not leave fragments
of petro-polymers in the soil.
The length of time it takes for oxo-biodegradable
plastic products to degrade can be �programmed'
at the time of manufacture and can be as little
as a few months or as much as a few years.
They can be opaque vacuum-packed for delivery
and will not degrade in the absence of air
and light, until needed for use.
Unlike PVC, the polymers from which oxo-biodegradable
plastics are made do not contain organo-chlorine.
Nor do oxo-biodegradable polymers emit methane
or nitrous oxide under aerobic or anaerobic
conditions.
Products can be made in oxo-biodegradable
plastic using the same machinery as currently
used for conventional plastic. There is therefore
no need to re-equip factories or re-train
the workforce.
Oxo-biodegradable plastics are made from a by-product of oil refining. Though
oil is a finite resource, this by-product
arises because the world needs fuels and oils
for engines, and would arise whether or not
the by-product were used to make plastic goods.
Unless the oil resources are left under the
ground, carbon dioxide will inevitably be
released, but until other fuels and lubricants
have been developed for engines, it makes
good environmental sense to use the by-product,
instead of wasting it by �flare-off� at the
refinery and emitting carbon dioxide to atmosphere
at that stage. As the labour, cost, and energy
required to produce the raw material for oxo-biodegradable
plastics is going to be incurred anyway in
the production of fuels, it cannot properly
be attributed to oxo-biodegradable plastics
in a Life-cycle Assessment.
Hydro -biodegradable or �starch-based� plastics made from
agricultural produce are not a preferred alternative.
They are not really �renewable� because the
process of making them from crops is itself
a significant user of hydrocarbon energy and
a producer therefore of greenhouse gases.
Hydrocarbons are burned by the autoclaves
used to ferment and polymerize material synthesized
from bio chemically produced intermediates
(e.g. polylactic acid from starch etc); and
by the agricultural machinery and road vehicles
employed; also by the manufacture and transport
of fertilisers and pesticides.
Hydro-biodegradable plastic emits methane
and carbon-di oxide (which are both greenhouse
gases) when it degrades, and does so much
more rapidly than oxo-biodegradable plastic.
Methane is 23 times more potent for global
warming than CO 2 . Hydro-biodegradable plastic
also contains a proportion of synthetic plastic
derived from oil. It is sometimes described
as made from �non-food� crops, but it is in
fact usually made from food crops such as
maize.
Also, for the reasons mentioned below, oxo-biodegradable products are in many respects more useful and cost-effective than degradable products made from agricultural ingredients.
Test results have demonstrated that oxo-biodegradable
plastic produces no immediate or cumulative
adverse effects on the soil, whether from
the plastic itself or from peroxidants, plasticisers,
surfactants, pigments, metals or lubricants.
The major elements of these latter materials
are naturally bio-degradable, and the traces
remaining after degradation are in such minor
parts per million (in some cases, per billion)
that no harmful effects will occur. These
materials can of course also be found in starch-based
products.
Starch-based plastics are known as �hydro-biodegradable.� They degrade by
a process that emits carbon dioxide rapidly
to the atmosphere. As compared with hydro-biodegradable,
the oxo-biodegradable plastics
have the following advantages:
They will degrade in any outdoor
or indoor environment, even in the absence
of water. This is a very important factor
in relation to litter,
because a large amount of plastic waste cannot
be collected. Most of the hydro-biodegradable
plastics need to be
in a highly microbial environment such as
a compost heap before they will degrade.
Oxo-biodegradable plastic can
be programmed at manufacture to degrade within
a timescale to suit the user's requirements.
The rate of degradation of hydro-biodegradable
plastics cannot be controlled.
Oxo-biodegradable plastics are
stronger and more versatile.
They are much cheaper
They are thinner, and use less
space to store and transport, and less material
to produce
They can be transparent, so that
the food or other contents within can be clearly
seen.
They can be recycled and can
be made from recyclate. Hydro-biodegradable
plastic cannot be made from recyclate, and
cannot be recycled unless extracted from the
plastic waste stream and treated separately.
They can both be composted, but
because the carbon is released more slowly
from oxo-biodegradable plastic, the carbon
becomes a food resource for growing plants.
Bags made from them do not leak
Less energy is required to produce
and transport them.
No genetically-modified ingredients
They do not emit methane
No residual plastic particles
No organo-chlorine
Safe for direct food contact
Ideal for frozen food because
they can be kept for long periods in sub-zero
temperatures and will not start to degrade
rapidly until the
frozen food has been used and the wrapper
has become waste.
They can be used in high-speed
machinery (such as for bread packaging) but
the performance of hydro- biodegradable
plastics in these machines is not acceptable.
They can be incinerated with
much higher energy-recovery than hydro-biodegradable
plastic
They can be made with the same
workforce and machinery as conventional plastic
products, but hydro-biodegradable products
are made by a quite different process.
It seems wrong to divert agricultural
resources away from food production when there
is so much hunger in the world, and
to use fertilisers and pesticides unnecessarily
The Report mentioned above on �The impacts
of degradable plastic bags in Australia� prepared
by ExcelPlas/ Nolan-ITU on 11 September 2003
for the Australian Government noted at 7.3
that:
degradable polymers with starch content
have higher impacts upon greenhouse due to
methane emissions during landfill degradation
and N 2 O emissions from fertilizing crops.
degradable polymers manufactured from
renewable resources (e.g., crops) have greater
impacts upon eutrophication due to the application
of fertilizers to land
Oxo biodegradable plastic is available in the following products:
Carrier bags or �shopper-bags� which consumers use to take away their purchases from the shop
Refuse sacks, which consumers buy in rolls at the shop, and use for disposal of their ordinary household waste.
Organic waste bags, similar to (b) above, which consumers use to dispose of their organic waste
Aprons, for the protection of garments, in the home, hospitals, restaurants, workshops etc.
Bags to contain dog faeces collected in parks, gardens, etc
Bin liners
Gloves
Hospital laundry bags in which soiled laundry can be put directly into a washing machine inside the bag
Plastic sheeting for a variety of applications in agriculture and horticulture.
Plastic film for wrapping newspapers and magazines.
Bread bags
Frozen food bags
Wrappers for cigarette packets
Shrink-wrap and pallet-wrap
Rigid products such as bottles and cups (currently in development)
�Bubble-wrap�
More products will become available in due course.
Oxo-biodegradable plastic can satisfy American
Standard ASTM D6954-04 for Plastics that Degrade
in the Environment by a Combination of Oxidation
and Biodegradation. It can also satisfy draft
British Standard 8472 for Compostability (including
biodegradability and eco-toxicity) of packaging
materials based on oxo-biodegradable plastics.
There is no European Standard for degradable
plastic except EN 13432, but this standard
applies only to composting of plastic
packaging . It is not appropriate
to oxo-biodegradable plastics, and was written
before they became popular.
In November 2004 a major conference was held
in Brussels at which scientists from around
the world acknowledged the benefits of oxo-biodegradable
plastic and recognised that a European standard
was needed for plastics that degrade by a
process of oxidation.
Oxo�biodegradable plastic made mainly from
polyolefin polymeric material is now very
widely accepted all over the World. It is
manufactured by Symphony Polymers of UK.
It is available in India by its agent called
Priti Plastics Pvt Ltd., Phone: +91-22-28614929
/ 28637432, Email: contact@pritigroup.com
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